Professor Andrei Malkov

Professor in Organic Chemistry and Head of Section
PhD (Moscow) MRSC

Telephone: +44(0)1509 22 2580
E-mail: A.Malkov@lboro.ac.uk

Group Page: click here

Research Area:

Synthetic Organic Chemistry
Asymmetric Catalysis

Research Topic:

Asymmetric organocatalysis
Transition metal catalysis
Design and synthesis of chiral catalysts
Reaction mechanisms
Synthesis of natural products

Selected Publications:

Malkov, A. V.; Kabeshov, M. A.; Barłog, M.; Kočovský, P. “Enantioselective and Catalytic Method for α-Crotylation of Aldehydes with a Kinetic Self-Refinement of Stereochemistry.” Chem. Eur. J. 2009, 15, 1570-1573.

A. V. Malkov, P. Ramírez-López, L. Biedermannova, L. Rulisek, L. Dufkova, M. Kotora, F. Zhu, P. Kočovský. “On the Mechanism of Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes Catalyzed by Quinox, a Chiral Isoquinoline N-Oxide.”J. Am. Chem. Soc. 2008, 130, 5341-5348.

A. V. Malkov, S. Stončius, P. Kočovský. "Enantioselective synthesis of 1,2-diarylaziridines via organocatalytic reductive amination of α-chloro ketones."Angew. Chem. Int. Ed. 2007, 46, 3722-3724.

A. V. Malkov, A. J. P. Stewart Liddon, P. Ramirez-Lopez, L. Bendová, D. Haigh, P. Kočovský. "Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines."Angew. Chem. Int. Ed. 2006, 45, 1432-1435.

Z. Bourhani, A. V. Malkov. "Ligand-accelerated V-catalysed epoxidation in water." Chem. Comm. 2005, 4592-4594.